Publication Catalysis 2009

F. Cardenas-Lizana, S. Gomez-Quero, G. Jacobs, Y. Ji, B. H. Davis, L. Kiwi-Minsker, M. A. Keane, J. Phys. Chem. C 2009, 116, 11166.

The catalytic gas phase hydrogenation of 1,3-dinitrobenzene over Au/Al2O3 delivered exclusive redn. of a single -NO2 substituent to generate 1,3-nitroaniline (Ea = 131 kJ mol-1), reaction over Ni/Al2O3 resulted in full hydrogenation to 1,3-phenylenediamine (Ea = 38 kJ mol-1), whereas both products were isolated over Au-Ni/Al2O3. In the hydrogenation of 1,3,5-trinitrobenzene, Au/Al2O3 promoted preferential partial hydrogenation (3,5-dinitroaniline), Ni/Al2O3 generated 1,3,5-triaminobenzene as the predominant product, while Au-Ni/Al2O3 exhibited an intermediate catalytic response. The catalysts were characterized in terms of temp. programmed redn. (TPR), H2 chemisorption, powder XRD, high-resoln. TEM, XPS, and XANES/EXAFS measurements. Post-TPR, there was evidence of a metal particle redispersion resulting from the introduction of Au to Ni/Al2O3 where HRTEM-EDX mapping established close proximity of Au and Ni on Au-Ni/Al2O3 with electron transfer from Ni to Au (from XPS anal.).

H chemisorption on Au-Ni/Al2O3 was 3 times lower than that recorded for Ni/Al2O3, suggesting Au-Ni interaction that inhibits H2 uptake. Simulation of the XANES/EXAFS response provided a better fit when incorporating Au-Ni interaction. The results demonstrate control of selectivity in poly nitroarene hydrogenation through the use of mono- (Au and Ni) and bi- (Au-Ni) metallic catalysts, where catalytic response is governed by surface compn.

10.1021/jp3025528

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