Publications
Selected Publications using Flowrence Technology
- Carvalho, Alexandre, Maya Marinova, Nuno Batalha, Nilson R. Marcilio, Andrei Y. Khodakov, and Vitaly V. Ordomsky. “Design of Nanocomposites with Cobalt Encapsulated in the Zeolite Micropores for Selective Synthesis of Isoparaffins in Fischer–Tropsch Reaction.” Sci. Technol. 7, no. 21 (2017): 5019–27. Link to publisher.
- Hernández Mejía, C., J. H. den Otter, J. L. Weber, and K. P. de Jong. “Crystalline Niobia with Tailored Porosity as Support for Cobalt Catalysts for the Fischer–Tropsch Synthesis.” Applied Catalysis A: General, Special issue in honor of Prof. Martin Schmal, 548, no. Supplement C (November 25, 2017): 143–49. Link to publisher.
- Luchters, Niels TJ, J. V. Fletcher, S. J. Roberts, and J. C. Q. Fletcher. “Variability of Data in High Throughput Experimentation for Catalyst Studies in Fuel Processing.” Bulletin of Chemical Reaction Engineering & Catalysis 12, no. 1 (2017): 106.
- Moonen, Roel, Jeroen Alles, Erik-jan Ras, Clare Harvey, and Jacob A. Moulijn. “Performance Testing of Hydrodesulfurization Catalysts Using a Single-Pellet-String Reactor.” Chemical Engineering & Technology 40, no. 11 (November 2017): 2025–34. Link to publisher.
- Munirathinam, Rajesh, Dorothée Laurenti, Denis Uzio, and Gerhard D. Pirngruber. “Do Happy Catalyst Supports Work Better? Surface Coating of Silica and Titania Supports with (Poly)Dopamine and Their Application in Hydrotreating.” Applied Catalysis A: General 544 (August 2017): 116–25. Link to publisher.
- Ordomsky, Vitaly V., and Andrei Y. Khodakov. “Syngas to Chemicals: The Incorporation of Aldehydes into Fischer-Tropsch Synthesis.” ChemCatChem 9, no. 6 (March 20, 2017): 1040–46. Link to publisher.
- Ordomsky, Vitaly V., Yuan Luo, Bang Gu, Alexandre Carvalho, Petr A. Chernavskii, Kang Cheng, and Andrei Y. Khodakov. “Soldering of Iron Catalysts for Direct Synthesis of Light Olefins from Syngas under Mild Reaction Conditions.” ACS Catalysis 7, no. 10 (October 6, 2017): 6445–52. Link to publisher.
- Botes, Gideon F., Tracy C. Bromfield, Roelof L.J. Coetzer, Renier Crous, Philip Gibson, and Alta C. Ferreira. “Development of a Chemical Selective Iron Fischer Tropsch Catalyst.” Catalysis Today 275 (October 2016): 40–48. Link to publisher.
- Cheng, Kang, Vijayanand Subramanian, Alexandre Carvalho, Vitaly V. Ordomsky, Ye Wang, and Andrei Y. Khodakov. “The Role of Carbon Pre-Coating for the Synthesis of Highly Efficient Cobalt Catalysts for Fischer–Tropsch Synthesis.” Journal of Catalysis 337 (May 2016): 260–71. Link to publisher.
- Delgado, Jorge A., Carmen Claver, Sergio Castillón, Daniel Curulla-Ferré, Vitaly V. Ordomsky, and Cyril Godard. “Effect of Polymeric Stabilizers on Fischer–Tropsch Synthesis Catalyzed by Cobalt Nanoparticles Supported on TiO2.” Journal of Molecular Catalysis A: Chemical 417 (June 2016): 43–52. Link to publisher.
- Laveille, Paco, Kevin Guillois, Alain Tuel, Corinne Petit, Jean-Marie Basset, and Valérie Caps. “Durable PROX Catalyst Based on Gold Nanoparticles and Hydrophobic Silica.” Chemical Communications 52, no. 15 (2016): 3179–82. Link to publisher.
- Murayama, Toru, Benjamin Katryniok, Svetlana Heyte, Marcia Araque, Satoshi Ishikawa, Franck Dumeignil, Sébastien Paul, and Wataru Ueda. “Role of Crystalline Structure in Allyl Alcohol Selective Oxidation over Mo 3 VO x Complex Metal Oxide Catalysts.” ChemCatChem 8, no. 14 (July 20, 2016): 2415–20. Link to publisher.
- Ordomsky, Vitaly V., Alexandre Carvalho, Benoit Legras, Sébastien Paul, Mirella Virginie, Vitaly L. Sushkevich, and Andrei Y. Khodakov. “Effects of Co-Feeding with Nitrogen-Containing Compounds on the Performance of Supported Cobalt and Iron Catalysts in Fischer–Tropsch Synthesis.” Catalysis Today 275 (October 2016): 84–93. Link to publisher.
- Oschatz, M., T. W. van Deelen, J. L. Weber, W. S. Lamme, G. Wang, B. Goderis, O. Verkinderen, A. I. Dugulan, and K. P. de Jong. “Effects of Calcination and Activation Conditions on Ordered Mesoporous Carbon Supported Iron Catalysts for Production of Lower Olefins from Synthesis Gas.” Sci. Technol. 6, no. 24 (2016): 8464–73. Link to publisher.
- Otter, Jan H. den, Sebastiaan R. Nijveld, and Krijn P. de Jong. “Synergistic Promotion of Co/SiO 2 Fischer–Tropsch Catalysts by Niobia and Platinum.” ACS Catalysis 6, no. 3 (March 4, 2016): 1616–23. Link to publisher.
- Otter, J.H. den, H. Yoshida, C. Ledesma, D. Chen, and K.P. de Jong. “On the Superior Activity and Selectivity of PtCo/Nb 2 O 5 Fischer Tropsch Catalysts.” Journal of Catalysis 340 (August 2016): 270–75. Link to publisher.
- Subramanian, Vijayanand, Kang Cheng, Christine Lancelot, Svetlana Heyte, Sébastien Paul, Simona Moldovan, Ovidiu Ersen, Maya Marinova, Vitaly V. Ordomsky, and Andrei Y. Khodakov. “Nanoreactors: An Efficient Tool To Control the Chain-Length Distribution in Fischer–Tropsch Synthesis.” ACS Catalysis 6, no. 3 (March 4, 2016): 1785–92. Link to publisher.
- Subramanian, Vijayanand, Vitaly V. Ordomsky, Benoit Legras, Kang Cheng, Catherine Cordier, Petr A. Chernavskii, and Andrei Y. Khodakov. “Design of Iron Catalysts Supported on Carbon–silica Composites with Enhanced Catalytic Performance in High-Temperature Fischer–Tropsch Synthesis.” Catalysis Science & Technology 6, no. 13 (2016): 4953–61. Link to publisher.
- Subramanian, Vijayanand, Vladimir L. Zholobenko, Kang Cheng, Christine Lancelot, Svetlana Heyte, Joelle Thuriot, Sébastien Paul, Vitaly V. Ordomsky, and Andrei Y. Khodakov. “The Role of Steric Effects and Acidity in the Direct Synthesis of Iso -Paraffins from Syngas on Cobalt Zeolite Catalysts.” ChemCatChem 8, no. 2 (January 2016): 380–89. Link to publisher.
- Cheng, Kang, Vitaly V. Ordomsky, Benoit Legras, Mirella Virginie, Sébastien Paul, Ye Wang, and Andrei Y. Khodakov. “Sodium-Promoted Iron Catalysts Prepared on Different Supports for High Temperature Fischer–Tropsch Synthesis.” Applied Catalysis A: General 502, no. Supplement C (August 5, 2015): 204–14. Link to publisher.
- Cheng, Kang, Mirella Virginie, Vitaly V. Ordomsky, Catherine Cordier, Petr A. Chernavskii, Mikhail I. Ivantsov, Sébastien Paul, Ye Wang, and Andrei Y. Khodakov. “Pore Size Effects in High-Temperature Fischer–Tropsch Synthesis over Supported Iron Catalysts.” Special Issue: The Impact of Haldor Topsøe on Catalysis 328, no. Supplement C (August 1, 2015): 139–50. Link to publisher.
- Eschemann, Thomas O., Wouter S. Lamme, Rene L. Manchester, Tanja E. Parmentier, Andrea Cognigni, Magnus Rønning, and Krijn P. de Jong. “Effect of Support Surface Treatment on the Synthesis, Structure, and Performance of Co/CNT Fischer–Tropsch Catalysts.” Special Issue: The Impact of Haldor Topsøe on Catalysis 328, no. Supplement C (August 1, 2015): 130–38. Link to publisher.
- Magendie, Guillaume, Bertrand Guichard, and Didier Espinat. “Effect of Acidity, Hydrogenating Phases and Texture Properties of Catalysts on the Evolution of Asphaltenes Structures during Reside Hydroconversion.” Selected Contributions in the Field of Heterogeneous Catalysis and Photocatalysis That Were Presented at the 8th International Conference on Environmental Catalysis (ICEC 2014) 258, no. Part 2 (December 1, 2015): 304–18. Link to publisher.
- Paul, Sébastien, Svetlana Heyte, Benjamin Katryniok, Cristina Garcia-Sancho, Pedro Maireles-Torres, and Franck Dumeignil. “REALCAT: A New Platform to Bring Catalysis to the Lightspeed.” Oil Gas Sci. Technol. – Rev. IFP Energies Nouvelles 70, no. 3 (2015): 455–62. Link to publisher.
- Zhu, Haibo, Paco Laveille, Devon C. Rosenfeld, Mohamed Nejib Hedhili, and Jean-Marie Basset. “A High-Throughput Reactor System for Optimization of Mo-V-Nb Mixed Oxide Catalyst Composition in Ethane ODH.” Catalysis Science & Technology 5, no. 8 (2015): 4164–73. Link to publisher.
- Cheng, K., V.V. Ordomsky, M. Virginie, B. Legras, P.A. Chernavskii, V.O. Kazak, C. Cordier, S. Paul, Ye Wang, and A.Y. Khodakov. “Support Effects in High Temperature Fischer-Tropsch Synthesis on Iron Catalysts.” Applied Catalysis A: General 488, no. Supplement C (November 1, 2014): 66–77. Link to publisher.
- Gerbasi da Silva, Arthur José, Paula Claassens-Dekker, Antônio Carlos Sallarès de Mattos Carvalho, Antônio Manzolillo Sanseverino, Cristina Pontes Bittencourt Quitete, Alexandre Szklo, and Eduardo Falabella Sousa-Aguiar. “Evaluation of MoS2 Based Catalysts for the Conversion of Syngas into Alcohols: A Combinatorial Approach.” Journal of Environmental Chemical Engineering 2, no. 4 (December 1, 2014): 2148–55. Link to publisher.
- Griboval-Constant, Anne, Aurore Butel, Vitaly V. Ordomsky, Petr. A. Chernavskii, and A.Y. Khodakov. “Cobalt and Iron Species in Alumina Supported Bimetallic Catalysts for Fischer–Tropsch Reaction.” Applied Catalysis A: General 481, no. Supplement C (July 5, 2014): 116–26. Link to publisher.
- Laveille, Paco, Gregory Biausque, Haibo Zhu, Jean-Marie Basset, and Valérie Caps. “A High-Throughput Study of the Redox Properties of Nb-Ni Oxide Catalysts by Low Temperature CO Oxidation: Implications in Ethane ODH.” 10th European Workshop Meeting on Selective Oxidation, The Silver Jubilee Meeting” Selectivity: The Key to Sustainability “. 203, no. Supplement C (March 30, 2013): 3–9. Link to publisher.
- Lok, C. Martin. “The 2014 Murray Raney Award Lecture: Architecture and Preparation of Supported Nickel Catalysts.” Topics in Catalysis 57, no. 17 (November 1, 2014): 1318–24. Link to publisher.
- Munnik, Peter, Petra E. de Jongh, and Krijn P. de Jong. “Control and Impact of the Nanoscale Distribution of Supported Cobalt Particles Used in Fischer–Tropsch Catalysis.” Journal of the American Chemical Society 136, no. 20 (May 21, 2014): 7333–40. Link to publisher.
- Munnik, Peter, Nynke A. Krans, Petra E. de Jongh, and Krijn P. de Jong. “Effects of Drying Conditions on the Synthesis of Co/SiO2 and Co/Al2O3 Fischer–Tropsch Catalysts.” ACS Catalysis 4, no. 9 (September 5, 2014): 3219–26. Link to publisher.
- Otter, Jan H. den, and Krijn P. de Jong. “Highly Selective and Active Niobia-Supported Cobalt Catalysts for Fischer–Tropsch Synthesis.” Topics in Catalysis 57, no. 6–9 (April 2014): 445–50. Link to publisher.
- Ras, Erik-Jan, and Santiago Gomez-Quero. “Oxidative Coupling of Methane in Small Scale Parallel Reactors.” Topics in Catalysis 57, no. 17 (November 1, 2014): 1392–99. Link to publisher.
- Ras, Erik-Jan, and Gadi Rothenberg. “Heterogeneous Catalyst Discovery Using 21st Century Tools: A Tutorial.” RSC Advances 4, no. 12 (2014): 5963. Link to publisher.
- Zhu, Haibo, Dalaver H. Anjum, Qingxiao Wang, Edy Abou-Hamad, Lyndon Emsley, Hailin Dong, Paco Laveille, Lidong Li, Akshaya K. Samal, and Jean-Marie Basset. “Sn Surface-Enriched Pt–Sn Bimetallic Nanoparticles as a Selective and Stable Catalyst for Propane Dehydrogenation.” Journal of Catalysis 320, no. Supplement C (December 1, 2014): 52–62. Link to publisher.
Publications
Performance Testing of Hydrodesulfurization Catalysts Using a Single-Pellet-String Reactor
Dedicated to Professor Rüdiger Lange on the occasion of his 65th birthday Small-scale parallel trickle-bed reactors were used to evaluate the performance of a commercial hydrodesulfurization catalyst under industrially relevant conditions. Catalyst extrudates were...
read moreNovel and Effective Copper-Aluminum Propane Dehydrogenation Catalysts
Publication Catalysis 2011 J. Schaeferhans, S. Gomez-Quero, D. V. Andreeva, G. Rothenberg, Chem.--Eur. J. 2011, 17, 12254. We report here a new effective Cu-Al catalyst for dehydrogenation of propane at low temp. The catalyst is oxidized porous alloy with the...
read moreProduction of Propylene from 1-Butene on Highly Active “Bi-Functional Single Active Site” Catalyst: Tungsten Carbene-Hydride Supported on Alumina
Publication Catalysis 2011 E. Mazoyer, K. C. Szeto, S. Norsic, A. Garron, J.-M. Basset, C. P. Nicholas, M. Taoufik, ACS Catal. 2011, 1, 1643. 1-Butene is transformed in a continuous flow reactor over tungsten hydride precursor W-H/Al2O3, giving a promising yield of...
read moreBeta-Molybdenum nitride: synthesis mechanism and catalytic response in the gas phase hydrogenation of p-chloronitrobenzene
Publication Catalysis 2011 F. Cardenas-Lizana, S. Gomez-Quero, N. Perret, L. Kiwi-Minsker, M. A. Keane, Catal. Sci. Technol. 2011, 1, 118. A temp. programmed treatment of MoO3 in flowing N2 + H2 has been employed to prep. β-phase molybdenum nitride (β-Mo2N) which...
read moreGold catalysis at the gas-solid interface: role of the support in determining activity and selectivity in the hydrogenation of m-dinitrobenzene
Publication Catalysis 2011 F. Cardenas-Lizana, S. Gomez-Quero, N. Perret, M. A. Keane, Catal. Sci. Technol. 2011, 1, 652. The catalytic gas phase hydrogenation of m-dinitrobenzene (1 atm, 423 K) over lab. synthesized (1 mol.%) Au supported on Al2O3, TiO2, Fe2O3, and...
read moreHeterogeneously Catalyzed Continuous-Flow Hydrogenation Using Segmented Flow in Capillary Columns
Publication Catalysis 2011 J. J. W. Bakker, M. M. P. Zieverink, R. W. E. G. Reintjens, F. Kapteijn, J. A. Moulijn, M. T. Kreutzer, ChemCatChem 2011, 3, 1155. This paper explores how the visible features of segmented-flow, under reaction conditions, can be used in...
read moreCombined ATR-FTIR and DFT Study of Cyclohexanone Adsorption on Hydrated TiO2 Anatase Surfaces
Publication Catalysis 2011 A. R. Almeida, M. Calatayud, F. Tielens, J. A. Moulijn, G. Mul, J. Phys. Chem. C 2011, 115, 14164. The adsorption of cyclohexanone on different planes ((100), (101), and (001)) of anatase TiO2, with variable level of hydration, was evaluated...
read morePhoto-catalytic oxidation of cyclohexane over TiO2: A novel interpretation of temperature dependent performance
Publication Catalysis 2011 A. R. Almeida, R. Berger, J. A. Moulijn, G. Mul, Phys. Chem. Chem. Phys. 2011, 13, 1345. The rate of cyclohexane photo-catalytic oxidn. to cyclohexanone over anatase TiO2 was studied at 23-60 °C by in situ ATR-FTIR spectroscopy, and the...
read moreHigh-throughput experimentation in syngas based research
Publication Catalysis 2011 J. K. van der Waal, G. Klaus, M. Smit, C. M. Lok, Catal. Today 2011, 171, 207. The potential of high-throughput technol. in studying catalysts and processes in syngas R&D was demonstrated through a series of Fischer-Tropsch studies. The...
read moreC. Martin Lok’s contribution to the industrial development of heterogeneous hydrogenation catalysts
Publication Catalysis 2011 Wicher T. Koetsier, Aalbert Zwijnenburg, Catalysis Today 2011, 163(1), 10. This contribution in the special issue of Catalysis Today aims to put the work of Martin Lok into historical perspective. It is shown that recent developments in...
read moreNew tricks by very old dogs: predicting the catalytic hydrogenation of HMF derivatives using Slater-type orbitals
Publication Catalysis 2012 Erik-Jan Ras, Manuel J. Louwerse, Gabi Rothenberg, Cat. Sci. Tech. 2012, 2(12), 2456. We report new experimental results on the hydrogenation of 5-ethoxymethylfurfural, an important intermediate in the conversion of sugars to industrial...
read moreCatalytic process development for renewable materials
Publication Catalysis 2013 eds. Pieter Imhof, Jan Cornelis van der Waal, John Wiley & Sons 2013, 370 p. Green, clean and renewable are the hottest keywords for catalysis and industry. This handbook and ready reference is the first to combine the fields of advanced...
read moreEvaluation of MoS2 based catalysts for the conversion of syngas into alcohols: A combinatorial approach
Publication Catalysis 2014 Arthur José Gerbasi da Silva, Paula Claassens-Dekker, Antônio Carlos Sallarès de Mattos Carvalho, Antônio Manzolillo Sanseverino, Cristina Pontes Bittencourt Quitete, Alexandre Szklo, Eduardo Falabella Sousa-Aguiar, J. Env. Chem....
read moreOxidative Coupling of Methane in Small Scale Parallel Reactors
Publication Catalysis 2014 Erik-Jan Ras, Santiago Gomez-Quero, Top. Catal. 2014, Vol. 57, p.1392 In this work the testing of high temperature reactions in small scale parallel reactors is explored using the oxidative coupling of methane as an example. The advantages...
read moreSelectivity and stability of zeolites [Ca]A and [Ag]A towards ethylene adsorption and desorption from complex gas mixtures
Ilona van Zandvoort, Gerard P.M. van Klink, Ed de Jong, Jan C. van der Waal, Microporous and Mesoporous Materials, June 2018, Volume 263, p. 142–149 Avantium Chemicals B.V., Zekeringstraat 29, 1014 BV Amsterdam, The Netherlands Received 27 July 2017, Revised 4...
read moreA comparative study of the selective oxidation of NH3 to N2 over gold, silver and copper catalysts and the effect of addition of Li2O and CeOx
Publication Catalysis 2008 M. J. Lippits, A. C. Gluhoi, B. E. Nieuwenhuys, Catal. Today 2008, 137, 446. The selective oxidn. of NH3 into N over Cu, Ag, and Au catalysts at room temp. to 400°C using different NH3:O2 ratios is described. The effect of adding CeOx and...
read moreIsoreticular MOFs as efficient photocatalysts with tunable band gap: an operando FTIR study of the photoinduced oxidation of propylene
Publication Catalysis 2008 J. Gascon, M. D. Hernandez-Alonso, A. R. Almeida, K. G. P. M. van, F. Kapteijn, G. Mul, ChemSusChem 2008, 1, 981. The first spectroscopic evidence of metal-org. frameworks (MOFs) acting as photocatalysts has been obtained. Isoreticular MOFs...
read moreBronsted-Evans-Polanyi Relation of Multistep Reactions and Volcano Curve in Heterogeneous Catalysis
Publication Catalysis 2008 J. Cheng, P. Hu, P. Ellis, S. French, G. Kelly, C. M. Lok, J. Phys. Chem. C 2008, 112, 1308. Multistep surface processes involving a no. of assocn. reactions and desorption processes may be considered as hypothetical one-step desorption...
read moreA First-Principles Study of Oxygenates on Co Surfaces in Fischer-Tropsch Synthesis
Publication Catalysis 2008 J. Cheng, P. Hu, P. Ellis, S. French, G. Kelly, C. M. Lok, J. Phys. Chem. C 2008, 112, 9464. Extensive d. function theory calcns. are performed to study the mechanism of the formation of aldehyde and alc. on Co surfaces in Fischer-Tropsch...
read moreAlumina-Supported Ni-Au: Surface Synergistic Effects in Catalytic Hydrodechlorination
Publication Catalysis 2009 M. A. Keane, S. Gomez-Quero, F. Cardenas-Lizana, W. Shen, ChemCatChem 2009, 1, 270. Catalytic gas-phase hydrodechlorination (HDC) of 2,4-dichlorophenol (2,4-DCP) has been investigated over Ni/Al2O3 and Au/Al2O3 prepd. by impregnation, and...
read moreSynthesis of high surface area cobalt-on-alumina catalysts by modification with organic compounds
Publication Catalysis 2009 P. R. Ellis, D. James, P. T. Bishop, J. L. Casci, C. M. Lok, G. J. Kelly, Chem. Ind. (Boca Raton, FL, U. S.) 2009, 128, 1. Cobalt-on-alumina catalysts with increased dispersion and catalytic activity are prepd. by addn. of mannitol to the...
read moreFischer-Tropsch catalysis: The basis for an emerging industry with origins in the early 20th Century
Publication Catalysis 2009 J. L. Casci, C. M. Lok, M. D. Shannon, Catal. Today 2009, 145, 38. A review of the discovery and development, including modern anal. and characterization techniques, of the Fischer-Tropsch reaction and assocd. catalysts. Fischer-Tropsch...
read moreAlumina Supported Au-Ni: Surface Synergism in the Gas Phase Hydrogenation of Nitro-Compounds
Publication Catalysis 2009 F. Cardenas-Lizana, S. Gomez-Quero, G. Jacobs, Y. Ji, B. H. Davis, L. Kiwi-Minsker, M. A. Keane, J. Phys. Chem. C 2009, 116, 11166. The catalytic gas phase hydrogenation of 1,3-dinitrobenzene over Au/Al2O3 delivered exclusive redn. of a...
read moreLocal, global and electronic structure of supported gold nanoclusters determined by EXAFS, XRD and XPS methods
Publication Catalysis 2009 N. Aldea, V. Rednic, S. Pintea, P. Marginean, B. Barz, A. Gluhoi, B. E. Nieuwenhuys, M. Neumann, Y. Xie, F. Matei, Superlattices Microstruct. 2009, 46, 141. We analyze gold nanoclusters as supported catalysts by extended X-ray absorption...
read moreAmmonia oxidation on Ir(1 1 1): Why Ir is more selective to N2 than Pt
Publication Catalysis 2010 C. J. Weststrate, J. W. Bakker, A. C. Gluhoi, W. Ludwig, B. E. Nieuwenhuys, Catal. Today 2010, 154, 46. NH3 does not dissoc. on a clean Ir(1 1 1) surface, but dissocn. can be induced by radiation, which yields all possible NHxad species....
read moreStability of metal nanoparticles formed during reduction of alumina supported nickel and cobalt catalysts
Publication Catalysis 2010 B. M. Vogelaar, A. D. van Langeveld, P. J. Kooyman, C. M. Lok, R. L. C. Bonne, J. A. Moulijn, Catal. Today 2010, 163, 20. The formation of nickel and cobalt nanoparticles in hydrogenation catalysts and their stability against sintering...
read moreHeteronuclear NMR Correlations To Probe the Local Structure of Catalytically Active Surface Aluminum Hydride Species on Alumina
Publication Catalysis 2010 E. Mazoyer, J. Trebosc, A. Baudouin, O. Boyron, J. Pelletier, J.-M. Basset, M. J. Vitorino, C. P. Nicholas, R. M. Gauvin, M. Taoufik, L. Delevoye, Angew. Chem., Int. Ed. 2010, 49, 9854. Heteronuclear NMR correlations to probe local structure...
read moreDevelopment of the first well-defined tungsten oxo alkyl derivatives supported on silica by SOMC: towards a model of WO3/SiO2 olefin metathesis catalyst
Publication Catalysis 2010 E. Mazoyer, N. Merle, A. de Mallmann, J.-M. Basset, E. Berrier, L. Delevoye, J.-F. Paul, C. P. Nicholas, R. M. Gauvin, M. Taoufik, Chem. Commun. (Cambridge, U. K.) 2010, 46, 8944. A well-defined, SiO2-supported W(O)Np3 (I; Np = CH2CMe3)...
read moreSolvent effects in the catalytic hydrotreament of haloaromatics over Pd/Al2O3 in water+organic mixtures
Publication Catalysis 2010 S. Gomez-Quero, E. Diaz, F. Cardenas-Lizana, M. A. Keane, Chem. Eng. Sci. 2010, 65, 3786. Solvent effects have been studied for the liq. phase (atm. pressure, T=303 K) hydrodehalogenation (HDH) of a range of haloarenes in methanol, THF,...
read moreGold, still a surprising catalyst: Selective hydrogenation of acetylene to ethylene over Au nanoparticles
Publication Catalysis 2010 A. C. Gluhoi, J. W. Bakker, B. E. Nieuwenhuys, Catal. Today 2010, 154, 13. The hydrogenation of C2H2 in the presence and the absence of C2H4 has been studied over un-promoted and promoted Au/Al2O3. A no. of parameters have been varied: the...
read moreSome Understanding of Fischer-Tropsch Synthesis from Density Functional Theory Calculations
Publication Catalysis 2010 J. Cheng, P. Hu, P. Ellis, S. French, G. Kelly, C. M. Lok, Top. Catal. 2010, 53, 326. A review. The combination of d. functional theory (DFT) calcns. and kinetic analyses is a very useful approach to study surface reactions in heterogeneous...
read morePromoted Iron Nanocrystals Obtained via Ligand Exchange as Active and Selective Catalysts for Synthesis Gas Conversion
Marianna Casavola, Jingxiu Xie, Johannes D. Meeldijk, Nynke A. Krans, Andrey Goryachev, Jan P. Hofmann, A. Iulian Dugulan, and Krijn P. de Jong, ACS Catal., 2017, 7 (8), p. 5121–5128 Colloidal synthesis routes have been recently used to fabricate heterogeneous...
read moreEffects of calcination and activation conditions on ordered mesoporous carbon supported iron catalysts for production of lower olefins from synthesis gas
M. Oschatz, T. W. van Deelen, J. L. Weber, W. S. Lamme, G. Wang, B. Goderis, O. Verkinderen, A. I. Dugulan and K. P. de Jong, Catal. Sci, Technol., 2016, 6, 8464-8473 Lower C2–C4 olefins are important commodity chemicals usually produced by steam cracking of naphtha...
read moreSyngas to Chemicals: The Incorporation of Aldehydes into Fischer–Tropsch Synthesis
Dr. Vitaly V. Ordomsky, Dr. Andrei Y. Khodakov, CHEMCATCHEM, March 2017, Volume 9, Issue 6, p. 1040-1046 Syngas is an important intermediate for the synthesis of chemicals and fuels; it can be produced from renewable and fossil feedstocks. Syngas conversion on Fe...
read moreEffects of the Functionalization of the Ordered Mesoporous Carbon Support Surface on Iron Catalysts for the Fischer–Tropsch Synthesis of Lower Olefins
Dr. Martin Oschatz, Dr. Jan P. Hofmann, Tom W. van Deelen, Wouter S. Lamme, Nynke A. Krans, Prof. Dr. Emiel J. M. Hensen, Prof. Dr. Krijn P. de, CHEMCATCHEM, February 2017, Volume 9, Issue 4, p. 620-628 Ordered mesoporous carbon (CMK-3) with different surface...
read moreOrdered Mesoporous Materials as Supports for Stable Iron Catalysts in the Fischer–Tropsch Synthesis of Lower Olefins
Dr. Martin Oschatz, Wouter S. Lamme, Jingxiu Xie, Dr. A. Iulian Dugulan, Prof. Dr. Krijn P. de Jong, CHEMCATCHEM, September 2016, Volume 8, Issue 17, p. 2846-2852 The Fe-catalyzed Fischer–Tropsch to olefins (FTO) synthesis is a non-oil-based route for the production...
read moreEffect of polymeric stabilizers on Fischer–Tropsch synthesis catalyzed by cobalt nanoparticles supported on TiO2
Jorge A.Delgado, Carmen Claver, Sergio Castillón, Daniel Curulla-Ferré, Vitaly V. Ordomsky, Cyril Godard, Journal of Molecular Catalysis A: Chemical, June 2016, Volume 417, p. 43-52 A series of colloidal cobalt nanoparticles of ca. 2.6 nm stabilized by several...
read moreDurable PROX catalyst based on gold nanoparticles and hydrophobic silica
Paco Laveille, Kevin Guillois, Alain Tuel, Corinne Petit, Jean-Marie Basset and Valérie Caps, Chemical Communications, 2016, 52, 3179-3182 3 nm gold nanoparticles obtained by direct chemical reduction of AuPPh3Cl in the presence of hydrophobic silica are highly active...
read moreThe Role of Steric Effects and Acidity in the Direct Synthesis of iso-Paraffins from Syngas on Cobalt Zeolite Catalysts
Dr. Vijayanand Subramanian, Prof. Vladimir L. Zholobenko, Dr. Kang Cheng, Dr. Christine Lancelot, Dr. Svetlana Heyte, Dr. Joelle Thuriot, Prof. Sébastien Paul, Dr. Vitaly V. Ordomsky, Dr. Andrei Y. Khodakov, CHEMCATCHEM, 2016, Volume 8, Issue 2, Pages 380–389 This...
read moreA high-throughput reactor system for optimization of Mo–V–Nb mixed oxide catalyst composition in ethane ODH
Haibo Zhu, Paco Laveille, Devon C. Rosenfeld, Mohamed Nejib Hedhili and Jean-Marie Basset, Catalysis Science & Technology, 2015, Issue 8 75 Mo–V–Nb mixed oxide catalysts with a broad range of compositions were prepared by a simple evaporation method, and were...
read moreSodium-promoted iron catalysts prepared on different supports for high temperature Fischer–Tropsch synthesis
Kang Cheng, Vitaly V. Ordomsky, Benoit Legras, Mirella Virginie, Sébastien Paul, Ye Wang, Andrei Y. Khodakova, Applied Catalysis A: General, August 2015, Volume 502, p. 204-214. The paper addresses the effect of sodium promotion on the structure and catalytic...
read morePore size effects in high-temperature Fischer–Tropsch synthesis over supported iron catalysts
Kang Cheng, Mirella Virginie, Vitaly V. Ordomsky, Catherine Cordier, Petr A. Chernavskii, Mikhail I. Ivantsov, Sébastien Paul, Ye Wang, Andrei Y. Khodakova, Journal of Catalysis, August 2015, Volume 328, p. 139-150. This paper addresses the effect of support pore...
read moreEffects of co-feeding with nitrogen-containing compounds on the performance of supported cobalt and iron catalysts in Fischer–Tropsch synthesis
Publication Utrecht University Vitaly V.Ordomsky, Alexander Carvalho, Benoit Legras, Sébastien Paul, Mirella Virginie, Vitaly L. Sushkevich, Andrei Y. Khodakov, Catalysis Today 2016, 15, 84-93. The performance of supported cobalt and iron catalysts in low and high...
read moreDurable PROX catalyst based on gold nanoparticles and hydrophobic silica
Publication Utrecht University Paco Laveille, Kevin Guillois, Alain Tuel, Corinne Petit, Jean-Marie Basseta and Valérie Caps, Chemical Communications 2016, 52 (15), 3179-3182. 3 nm gold nanoparticles obtained by direct chemical reduction of AuPPh3Cl in the presence of...
read moreSynergistic Promotion of Co/SiO2 Fischer–Tropsch Catalysts by Niobia and Platinum
Publication Utrecht University Jan H. den Otter, Sebastiaan R. Nijveld, and Krijn P. de Jong, ACS Catalysis 2016, 6 (3), 1616-1623. Transition-metal oxides and noble metals are well-known selectivity and activity promoters in cobalt-based Fischer–Tropsch catalysis....
read moreRole of Crystalline Structure in Allyl Alcohol Selective Oxidation over Mo3VOx Complex Metal Oxide Catalysts
Publication Utrecht University Prof. Dr. Toru Murayama, Dr. Benjamin Katryniok, Dr. Svetlana Heyte, Dr. Marcia Araque, Dr. Satoshi Ishikawa, Prof. Dr. Franck Dumeignil, Prof. Dr. Sébastien Paul, Prof. Dr. Wataru Ueda, Chem Cat Chem Catalysis 2016, 8 (14), 2415-2420....
read moreOn the superior activity and selectivity of PtCo/Nb2O5 Fischer Tropsch catalysts
Publication by customer J.H. den Otter, H. Yoshida, C. Ledesma, D. Chen, K.P. de Jong, Journal of Catalysis 2016, 340, 270-275. In this study Co/Nb2O5 catalysts and the effect of Pt-promotion thereon are investigated in comparison with γ-Al2O3- and α-Al2O3-supported...
read moreOrdered Mesoporous Materials as Supports for Stable Iron Catalysts in the Fischer–Tropsch Synthesis of Lower Olefins
Publication by customer Dr. Martin Oschatz, Wouter S. Lamme, Jingxiu Xie, Dr. A. Iulian Dugulan, Prof. Dr. Krijn P. de Jong, Chem Cat Chem Catalysis 2016, 8 (17), 2846-2852. The Fe-catalyzed Fischer–Tropsch to olefins (FTO) synthesis is a non-oil-based route for the...
read moreEffects of the Functionalization of the Ordered Mesoporous Carbon Support Surface on Iron Catalysts for the Fischer–Tropsch Synthesis of Lower Olefins
Publication by customer Dr. Martin Oschatz, Dr. Jan P. Hofmann, Tom W. van Deelen, Wouter S. Lamme, Nynke A. Krans, Prof. Dr. Emiel J. M. Hensen, Prof. Dr. Krijn P. de Jong, Chem Cat Chem Catalysis 2017, 9 (4), 620-628. Ordered mesoporous carbon (CMK-3) with different...
read moreSyngas to Chemicals: The Incorporation of Aldehydes into Fischer–Tropsch Synthesis
Publication by customer Dr. Vitaly V. Ordomsky, Dr. Andrei Y. Khodakov, Chem Cat Chem Catalysis, 2017, 9 (6), 1040-1046. Syngas is an important intermediate for the synthesis of chemicals and fuels; it can be produced from renewable and fossil feedstocks. Syngas...
read moreEffects of calcination and activation conditions on ordered mesoporous carbon supported iron catalysts for production of lower olefins from synthesis gas
Publication by customer M. Oschatz, T. W. van Deelen, J. L. Weber, W. S. Lamme, G. Wang, B. Goderis, O. Verkinderen, A. I. Dugulan and K. P. de Jong, Catal. Sci. Tehnol., 2016, 6, 8464-8473. Lower C2–C4 olefins are important commodity chemicals usually produced by...
read moreEthanol-to-Hydrocarbons reaction catalysed by ion-exchanged ZSM-5 zeolites
Publication by customer Maha Ammoury, Benjamin Katryniok, Svetlana Heyte, Sébastian Paul, Franck Dumeignil, Mickaël Capron, Guillaume Pomalaza, Kenichi Shimizu, 8th International Symposium on Acid-Base Catalysis, May 7-10th, 2017, Rio de Janeiro - Brazil. Propene is...
read moreDo happy catalyst supports work better? Surface coating of silica and titania supports with (poly)dopamine and their application in hydrotreating
Publication by customer Rajesh Munirathinam, Dorothée Laurenti, Denis Uzio, Gerhard D. Pirngruber, Applied Catalysis A: General, 2017, Volume 544, 116-125. In order to meet the demand for cleaner fuels, it is necessary to develop high performing hydrotreating...
read morePromoted Iron Nanocrystals Obtained via Ligand Exchange as Active and Selective Catalysts for Synthesis Gas Conversion
Publication by customer Marianna Casavola, Jingxiu Xie, Johannes D. Meeldijk, Nynke A. Krans, Andrey Goryachev, Jan P. Hofmann, A. Lulian Dugulan and Krijn P. de Jong, ACS Catalysis 2017, 7, pp 5121-5128. Colloidal synthesis routes have been recently used to fabricate...
read moreEffects of noble metal promotion for Co/TiO2 Fischer-Tropsch catalysts
Publication Utrecht University Thomas O. Eschemann, Jogchum Oenema, Krijn P. de Jong, Catalysis Today 2016, 261, 60-66. The Fischer-TRopsch reaction involves the conversion of synthesis gas to higher hydrocarbons, which can then further be converted to ultraclean...
read moreDeactivation Behavior of Co/TiO2 Catalysts during Fischer–Tropsch Synthesis
Publication Utrecht University Thomas O. Eschemann and Krijn P. de Jong, ACS Catalysis 2015, 5 (6), 3181-3188. Here we report on the preparation of Co/TiO2 catalysts (8 and 16 wt % Co) using deposition precipitation by ammonia evaporation (DPA) and incipient wetness...
read morePore size effects in high-temperature Fischer–Tropsch synthesis over supported iron catalysts
Publication a.o. Université Lille Kang Cheng, Mirella Virginie, Vitaly V. Ordomsky, Catherine Cordier, Petr A. Chernavskii, Mikhail I. Ivantsov, Sébastien Paul, Ye Wang, Andrei Y. Khodakov, Journal of Catalysis 2015, Volume 328, 139-150. This paper addresses the...
read moreEffect of support surface treatment on the synthesis, structure, and performance of Co/CNT Fischer–Tropsch catalysts
Publication Utrecht University Thomas O. Eschemann, Wouter S. Lamme, Rene L. Manchester, Tanja E. Parmentier, Andrea Cognigni, Magnus Rønning, Krijn P. de Jong, Journal of Catalysis 2015, Volume 328, 130-138. We report the preparation of supported cobalt catalysts (9...
read moreSodium-promoted iron catalysts prepared on different supports for high temperature Fischer–Tropsch synthesis
Publication Université Lille Kang Cheng, Vitaly V. Ordomsky, Benoit Legras, Mirella Virginie, Sébastien Paul, Ye Wang, Andrei Y. Khodakov, Applied Catalysis A: General 2015, Volume 502, 204-214. The paper addresses the effect of sodium promotion on the structure and...
read moreHigh-throughput reactor system for optimization of Mo-V-Nb mixed oxide catalysts composition in ethane ODH
Publication KAUST Jean-Marie Basset, Haibo Zhu, Paco Victor Laveille, Devon C. Rosenfeld and Mohamed Nejib Hedhili, Cat. Sci. Tech. 2015, 5, 4164-4173. 75 Mo-V-Nb mixed oxide catalysts with a broad range of compositions were prepared by a simple evaporation method,...
read moreEffects of noble metal promotion for Co/TiO2 Fischer-Tropsch catalysts
Publication Utrecht University Thomas O. Eschemann, Jogchum Oenema, Krijn P. de Jong, Catalysis Today 2015, in press....
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